Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field

This paper describes the measurement of size distribution of TiO2 fine particles in a highly concentrated non-aqueous suspension by using self-assembly of particles under an electric field. Interactive force apparatus (IFA) was used to conduct the measurement. IFA first assembled pearl chains of par...

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Main Authors: Otsuki, Akira, Dodbiba, G., Fujita, T.
Other Authors: G.V Franks
Format: Conference Paper
Published: Elsevier BV 2012
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/16334
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author Otsuki, Akira
Dodbiba, G.
Fujita, T.
author2 G.V Franks
author_facet G.V Franks
Otsuki, Akira
Dodbiba, G.
Fujita, T.
author_sort Otsuki, Akira
building Curtin Institutional Repository
collection Online Access
description This paper describes the measurement of size distribution of TiO2 fine particles in a highly concentrated non-aqueous suspension by using self-assembly of particles under an electric field. Interactive force apparatus (IFA) was used to conduct the measurement. IFA first assembled pearl chains of particles between two electrodes, and then applied the compressive force to change the pearl chain structure by shortening the distance between electrodes. The repulsive force generated when the chain curved while the attractive force created when the chain was broken. The cycle of repulsive and attractive forces corresponds to the size of particles. The results obtained with IFA were compared with results obtained from size measurement by analyzing SEM photographs. IFA indicated the comparable results with the one obtained using SEM. The particle size distribution measured by IFA decreased as a result of increasing the supply voltages. Changes in correlation between size distribution measured by SEM and IFA at different supply voltages were observed in different size ranges. At smaller than 300 nm, result at 0.24 V fit well with the SEM result while at >600 nm gives better agreement with the results at 0.48 V. The difference is mainly due to the increase in number of particles in fine size fraction with increasing supply voltages. Decrease in size indicated that the breakage of aggregate particles and/or disintegration of doublet particles occurred due to the electrical fragmentation. The fragmentation was explained by monitoring the mean diameters and their deviation obtained from IFA measurements at different supply voltages.
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institution Curtin University Malaysia
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publishDate 2012
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spelling curtin-20.500.11937-163342023-02-02T07:57:38Z Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field Otsuki, Akira Dodbiba, G. Fujita, T. G.V Franks Particle size distribution non-aqueous solvent titanium dioxide submicron particles electric breakdown interactive force apparatus electric field This paper describes the measurement of size distribution of TiO2 fine particles in a highly concentrated non-aqueous suspension by using self-assembly of particles under an electric field. Interactive force apparatus (IFA) was used to conduct the measurement. IFA first assembled pearl chains of particles between two electrodes, and then applied the compressive force to change the pearl chain structure by shortening the distance between electrodes. The repulsive force generated when the chain curved while the attractive force created when the chain was broken. The cycle of repulsive and attractive forces corresponds to the size of particles. The results obtained with IFA were compared with results obtained from size measurement by analyzing SEM photographs. IFA indicated the comparable results with the one obtained using SEM. The particle size distribution measured by IFA decreased as a result of increasing the supply voltages. Changes in correlation between size distribution measured by SEM and IFA at different supply voltages were observed in different size ranges. At smaller than 300 nm, result at 0.24 V fit well with the SEM result while at >600 nm gives better agreement with the results at 0.48 V. The difference is mainly due to the increase in number of particles in fine size fraction with increasing supply voltages. Decrease in size indicated that the breakage of aggregate particles and/or disintegration of doublet particles occurred due to the electrical fragmentation. The fragmentation was explained by monitoring the mean diameters and their deviation obtained from IFA measurements at different supply voltages. 2012 Conference Paper http://hdl.handle.net/20.500.11937/16334 10.1016/j.apt.2012.05.006 Elsevier BV restricted
spellingShingle Particle size distribution
non-aqueous solvent
titanium dioxide submicron particles
electric breakdown
interactive force apparatus
electric field
Otsuki, Akira
Dodbiba, G.
Fujita, T.
Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field
title Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field
title_full Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field
title_fullStr Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field
title_full_unstemmed Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field
title_short Measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field
title_sort measurements of size distribution of titanium dioxide fine particles in a highly concentrated non-aqueous suspension by using particle self-assembly under an electric field
topic Particle size distribution
non-aqueous solvent
titanium dioxide submicron particles
electric breakdown
interactive force apparatus
electric field
url http://hdl.handle.net/20.500.11937/16334