Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst

Australia mallee wood, bark and leaf samples (Eucalyptus loxophleba, subspecies lissophloia) werepyrolyzed to produce volatiles for in situ catalytic steam reforming with ilmenite as a catalyst. The results demonstrated that the properties of biomass feedstock (wood, bark and leaves) significantly i...

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Main Authors: Min, Zhenhua, Yimsiri, P., Zhang, Shu, Wang, Yi, Asadullah, Mohammad, Li, Chun-Zhu
Format: Journal Article
Published: Elsevier Science Ltd 2013
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/16272
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author Min, Zhenhua
Yimsiri, P.
Zhang, Shu
Wang, Yi
Asadullah, Mohammad
Li, Chun-Zhu
author_facet Min, Zhenhua
Yimsiri, P.
Zhang, Shu
Wang, Yi
Asadullah, Mohammad
Li, Chun-Zhu
author_sort Min, Zhenhua
building Curtin Institutional Repository
collection Online Access
description Australia mallee wood, bark and leaf samples (Eucalyptus loxophleba, subspecies lissophloia) werepyrolyzed to produce volatiles for in situ catalytic steam reforming with ilmenite as a catalyst. The results demonstrated that the properties of biomass feedstock (wood, bark and leaves) significantly influenced their product yields and properties. Bark produced the highest amounts of solid products, whereas leaf generated the highest amounts of tar during pyrolysis. The differences in the chemical composition and the tar yields among wood, bark and leaf decreased with increasing temperature. It is also found that ilmenite showed good activity for the reforming of all tars from different parts of mallee trees. However, its activity for reforming tar from bark and leaf decreased with prolonging feeding time due to their high gradual coke deposits. Compared with sintering, the accumulated coke deposited on ilmenite is a dominant factor to its deactivation during the steam reforming process. Burning coke is an effective method to regenerate the catalyst activity of ilmenite.
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institution Curtin University Malaysia
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publishDate 2013
publisher Elsevier Science Ltd
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spelling curtin-20.500.11937-162722017-02-28T01:26:25Z Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst Min, Zhenhua Yimsiri, P. Zhang, Shu Wang, Yi Asadullah, Mohammad Li, Chun-Zhu Ilmenite Aromatic ring systems Bark Steam reforming Leaf Australia mallee wood, bark and leaf samples (Eucalyptus loxophleba, subspecies lissophloia) werepyrolyzed to produce volatiles for in situ catalytic steam reforming with ilmenite as a catalyst. The results demonstrated that the properties of biomass feedstock (wood, bark and leaves) significantly influenced their product yields and properties. Bark produced the highest amounts of solid products, whereas leaf generated the highest amounts of tar during pyrolysis. The differences in the chemical composition and the tar yields among wood, bark and leaf decreased with increasing temperature. It is also found that ilmenite showed good activity for the reforming of all tars from different parts of mallee trees. However, its activity for reforming tar from bark and leaf decreased with prolonging feeding time due to their high gradual coke deposits. Compared with sintering, the accumulated coke deposited on ilmenite is a dominant factor to its deactivation during the steam reforming process. Burning coke is an effective method to regenerate the catalyst activity of ilmenite. 2013 Journal Article http://hdl.handle.net/20.500.11937/16272 Elsevier Science Ltd restricted
spellingShingle Ilmenite
Aromatic ring systems
Bark
Steam reforming
Leaf
Min, Zhenhua
Yimsiri, P.
Zhang, Shu
Wang, Yi
Asadullah, Mohammad
Li, Chun-Zhu
Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst
title Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst
title_full Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst
title_fullStr Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst
title_full_unstemmed Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst
title_short Catalytic reforming of tar during gasification. Part III. Effects of feedstock on tar reforming using ilmenite as a catalyst
title_sort catalytic reforming of tar during gasification. part iii. effects of feedstock on tar reforming using ilmenite as a catalyst
topic Ilmenite
Aromatic ring systems
Bark
Steam reforming
Leaf
url http://hdl.handle.net/20.500.11937/16272