One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation

© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimMoS2/g-CNO (g-CNO = oxidized graphitic carbon nitride) heterostructures were synthesized by a one-step low-temperature hydrothermal route. The hydrolysis and oxidation reactions during the hydrothermal synthesis provide a fivefold increase in the...

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Main Authors: Joy, M., Nair, Balagopal, Mohamed, A., Warrier, K., Hareesh, U.
Format: Journal Article
Published: Wiley - V C H Verlag GmbH 2016
Online Access:http://hdl.handle.net/20.500.11937/15251
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author Joy, M.
Nair, Balagopal
Mohamed, A.
Warrier, K.
Hareesh, U.
author_facet Joy, M.
Nair, Balagopal
Mohamed, A.
Warrier, K.
Hareesh, U.
author_sort Joy, M.
building Curtin Institutional Repository
collection Online Access
description © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimMoS2/g-CNO (g-CNO = oxidized graphitic carbon nitride) heterostructures were synthesized by a one-step low-temperature hydrothermal route. The hydrolysis and oxidation reactions during the hydrothermal synthesis provide a fivefold increase in the surface area of the carbon nitride matrix. The heterostructure formation between MoS2 and the g-CNO matrix induced reduced recombination effects, and 1 wt.-% MoS2/g-CNO composites showed the highest photocatalytic activity towards the degradation of organic pollutants under visible-light irradiation. Moreover, owing to the presence of groups with negative inductive effects in g-CNO and g-CNO-based composites, the photocatalytic activities were higher than that of bare g-C3N4. Recyclability studies on the synthesized catalysts indicated no loss of efficiency after four cycles. Thus, these MoS2/g-CNO heterostructures are promising photocatalysts for the degradation of organic pollutants.
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spelling curtin-20.500.11937-152512017-09-13T13:41:02Z One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation Joy, M. Nair, Balagopal Mohamed, A. Warrier, K. Hareesh, U. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimMoS2/g-CNO (g-CNO = oxidized graphitic carbon nitride) heterostructures were synthesized by a one-step low-temperature hydrothermal route. The hydrolysis and oxidation reactions during the hydrothermal synthesis provide a fivefold increase in the surface area of the carbon nitride matrix. The heterostructure formation between MoS2 and the g-CNO matrix induced reduced recombination effects, and 1 wt.-% MoS2/g-CNO composites showed the highest photocatalytic activity towards the degradation of organic pollutants under visible-light irradiation. Moreover, owing to the presence of groups with negative inductive effects in g-CNO and g-CNO-based composites, the photocatalytic activities were higher than that of bare g-C3N4. Recyclability studies on the synthesized catalysts indicated no loss of efficiency after four cycles. Thus, these MoS2/g-CNO heterostructures are promising photocatalysts for the degradation of organic pollutants. 2016 Journal Article http://hdl.handle.net/20.500.11937/15251 10.1002/ejic.201600232 Wiley - V C H Verlag GmbH restricted
spellingShingle Joy, M.
Nair, Balagopal
Mohamed, A.
Warrier, K.
Hareesh, U.
One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation
title One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation
title_full One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation
title_fullStr One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation
title_full_unstemmed One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation
title_short One-Pot Hydrothermal Synthesis of Visible-Light-Responsive MoS2/g-CNO Heterostructures for Organic-Pollutant Degradation
title_sort one-pot hydrothermal synthesis of visible-light-responsive mos2/g-cno heterostructures for organic-pollutant degradation
url http://hdl.handle.net/20.500.11937/15251