Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine
From the reaction of biguanide with ethyl benzoylacetate, N-(6-oxo-4-phenyl-1,6-dihydropyrimidin-2-yl)guanidine and 6-benzoylmethyl-1,3,5-triazin-2,4-diamine were isolated.The structural evaluation of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine was performed theoretically (DFT calculations) and experi...
| Main Authors: | , , |
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| Format: | Journal Article |
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Elsevier SAS
2011
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| Online Access: | http://hdl.handle.net/20.500.11937/14796 |
| _version_ | 1848748718857125888 |
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| author | Sachdeva, N. Dolzhenko, Anton Chui, W. |
| author_facet | Sachdeva, N. Dolzhenko, Anton Chui, W. |
| author_sort | Sachdeva, N. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | From the reaction of biguanide with ethyl benzoylacetate, N-(6-oxo-4-phenyl-1,6-dihydropyrimidin-2-yl)guanidine and 6-benzoylmethyl-1,3,5-triazin-2,4-diamine were isolated.The structural evaluation of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine was performed theoretically (DFT calculations) and experimentally (NMR spectroscopy and X-ray crystallography). The effects of solvents and temperature on keto-enol-enaminone tautomeric equilibrium were explored. |
| first_indexed | 2025-11-14T07:09:30Z |
| format | Journal Article |
| id | curtin-20.500.11937-14796 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:09:30Z |
| publishDate | 2011 |
| publisher | Elsevier SAS |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-147962017-09-13T15:54:45Z Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine Sachdeva, N. Dolzhenko, Anton Chui, W. X-ray crystal structure Solvent effect DFT calculations Triazines Tautomerism Resonance-assisted hydrogenbonding From the reaction of biguanide with ethyl benzoylacetate, N-(6-oxo-4-phenyl-1,6-dihydropyrimidin-2-yl)guanidine and 6-benzoylmethyl-1,3,5-triazin-2,4-diamine were isolated.The structural evaluation of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine was performed theoretically (DFT calculations) and experimentally (NMR spectroscopy and X-ray crystallography). The effects of solvents and temperature on keto-enol-enaminone tautomeric equilibrium were explored. 2011 Journal Article http://hdl.handle.net/20.500.11937/14796 10.1016/j.crci.2010.10.003 Elsevier SAS restricted |
| spellingShingle | X-ray crystal structure Solvent effect DFT calculations Triazines Tautomerism Resonance-assisted hydrogenbonding Sachdeva, N. Dolzhenko, Anton Chui, W. Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine |
| title | Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine |
| title_full | Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine |
| title_fullStr | Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine |
| title_full_unstemmed | Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine |
| title_short | Synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine |
| title_sort | synthesis and tautomerism study of 6-benzoylmethyl-1,3,5-triazin-2,4-diamine |
| topic | X-ray crystal structure Solvent effect DFT calculations Triazines Tautomerism Resonance-assisted hydrogenbonding |
| url | http://hdl.handle.net/20.500.11937/14796 |