Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume
Groups of structurally related materials, including the alkali halides, exhibit a proportionality of isothermal compressibility to formula-unit volume. The relationship has recently been explored by Glasser and by Recio et al. In this paper, we present the consequences of such proportionality on th...
| Main Authors: | , , |
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| Format: | Journal Article |
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American Chemical Society
2010
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| Online Access: | http://hdl.handle.net/20.500.11937/14278 |
| _version_ | 1848748580618108928 |
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| author | Jenkins, H. Glasser, Leslie Lee, J. |
| author_facet | Jenkins, H. Glasser, Leslie Lee, J. |
| author_sort | Jenkins, H. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Groups of structurally related materials, including the alkali halides, exhibit a proportionality of isothermal compressibility to formula-unit volume. The relationship has recently been explored by Glasser and by Recio et al. In this paper, we present the consequences of such proportionality on the relationships of Born-Lande and Born-Mayer parameters to the formula-unit volume. These relationships have then been tested separately on (i) alkali (excluding cesium) halides and (ii) cesium halides.We conclude that the equations fit the NaCl-type materials satisfactorily, but less well for the CsCl-type materials, and that the Born-Mayer equation is more applicable. These results confirm the conclusion that volume is intimately linked to thermodynamic quantities, as already demonstrated by our development of volume-based thermodynamics (VBT). |
| first_indexed | 2025-11-14T07:07:18Z |
| format | Journal Article |
| id | curtin-20.500.11937-14278 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:07:18Z |
| publishDate | 2010 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-142782017-09-13T16:02:00Z Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume Jenkins, H. Glasser, Leslie Lee, J. Groups of structurally related materials, including the alkali halides, exhibit a proportionality of isothermal compressibility to formula-unit volume. The relationship has recently been explored by Glasser and by Recio et al. In this paper, we present the consequences of such proportionality on the relationships of Born-Lande and Born-Mayer parameters to the formula-unit volume. These relationships have then been tested separately on (i) alkali (excluding cesium) halides and (ii) cesium halides.We conclude that the equations fit the NaCl-type materials satisfactorily, but less well for the CsCl-type materials, and that the Born-Mayer equation is more applicable. These results confirm the conclusion that volume is intimately linked to thermodynamic quantities, as already demonstrated by our development of volume-based thermodynamics (VBT). 2010 Journal Article http://hdl.handle.net/20.500.11937/14278 10.1021/ic101398g American Chemical Society restricted |
| spellingShingle | Jenkins, H. Glasser, Leslie Lee, J. Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume |
| title | Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume |
| title_full | Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume |
| title_fullStr | Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume |
| title_full_unstemmed | Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume |
| title_short | Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume |
| title_sort | volume-based thermoelasticity: consequences of the (near) proportionality of isothermal compressibility to formula-unit volume |
| url | http://hdl.handle.net/20.500.11937/14278 |