Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion
The formation of a cyclophane-NHC complex of Pd-(II) Via oxidatiVe addition of a C-C bond in a bridged biimidazolium ion to Pd(0) is described. The actiVe Pd(0) species appears to be [Pd(PPh3)2Br]-. Simple (unbridged) biimidazolium ions do not form NHC complexes under similar conditions.
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Published: |
American Chemical Society
2007
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| Online Access: | http://hdl.handle.net/20.500.11937/12957 |
| _version_ | 1848748220125020160 |
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| author | Baker, M. Brown, David Hesler, V. Skelton, B. White, A. |
| author_facet | Baker, M. Brown, David Hesler, V. Skelton, B. White, A. |
| author_sort | Baker, M. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The formation of a cyclophane-NHC complex of Pd-(II) Via oxidatiVe addition of a C-C bond in a bridged biimidazolium ion to Pd(0) is described. The actiVe Pd(0) species appears to be [Pd(PPh3)2Br]-. Simple (unbridged) biimidazolium ions do not form NHC complexes under similar conditions. |
| first_indexed | 2025-11-14T07:01:34Z |
| format | Journal Article |
| id | curtin-20.500.11937-12957 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:01:34Z |
| publishDate | 2007 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-129572017-09-13T15:01:40Z Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion Baker, M. Brown, David Hesler, V. Skelton, B. White, A. The formation of a cyclophane-NHC complex of Pd-(II) Via oxidatiVe addition of a C-C bond in a bridged biimidazolium ion to Pd(0) is described. The actiVe Pd(0) species appears to be [Pd(PPh3)2Br]-. Simple (unbridged) biimidazolium ions do not form NHC complexes under similar conditions. 2007 Journal Article http://hdl.handle.net/20.500.11937/12957 10.1021/om0610546 American Chemical Society restricted |
| spellingShingle | Baker, M. Brown, David Hesler, V. Skelton, B. White, A. Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion |
| title | Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion |
| title_full | Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion |
| title_fullStr | Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion |
| title_full_unstemmed | Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion |
| title_short | Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion |
| title_sort | synthesis of a bis(nhc)pd complex via oxidative addition of a c-c bond in a biimidazolium ion |
| url | http://hdl.handle.net/20.500.11937/12957 |