Crystal structure of anhydrous potassium O-n-propyldithiocarbonate. Theoretical calculations of O-alkyl dithiocarbonates

Crystal structure of anhydrous potassium O-n-propyldithiocarbonate. Theoretical calculations of O-alkyl dithiocarbonates

The xanthate anion in the structure of K[S(2)COnPr] displays the expected features, i.e. planar S2CO chromophore and variation in C-S and C-O distances. The K cation exists in a distorted cubic geometry defined by an O2S6 donor set. Cubes are face-shared so as to form a layer structure with cohesion...

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Bibliographic Details
Main Authors: Buntine, Mark, Cox, M., Lim, Y., Yap, T., Tiekink, E.
Format: Journal Article
Published: R Oldenbourg Verlag 2003
Subjects:
Ethylxanthate
Complexes
Effective core potentials
Methyldithiocarbonate
Packing
Molecular calculations
Online Access:http://hdl.handle.net/20.500.11937/12669

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