Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures

Understanding the nature of organic matter is a necessary first step in assessing contaminant bioavailability and allowing water supply managers to optimise the treatment train in the aim of providing safe and inexpensive drinking water. This study provides further insight into the composition, stru...

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Main Authors: Pernet-Coudrier, B., Varrault, G., Saad, M., Croue, Jean-Philippe, Dignac, M., Mouchel, J.
Format: Journal Article
Published: 2011
Online Access:http://hdl.handle.net/20.500.11937/12544
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author Pernet-Coudrier, B.
Varrault, G.
Saad, M.
Croue, Jean-Philippe
Dignac, M.
Mouchel, J.
author_facet Pernet-Coudrier, B.
Varrault, G.
Saad, M.
Croue, Jean-Philippe
Dignac, M.
Mouchel, J.
author_sort Pernet-Coudrier, B.
building Curtin Institutional Repository
collection Online Access
description Understanding the nature of organic matter is a necessary first step in assessing contaminant bioavailability and allowing water supply managers to optimise the treatment train in the aim of providing safe and inexpensive drinking water. This study provides further insight into the composition, structure and functional groups of dissolved organic matter (DOM) (both hydrophobic and hydrophilic) from urban aquatic systems by means of various analytical techniques (DAX-8/XAD-4 fractionation, elemental analysis, UV and FTIR spectroscopies, 13C and 15N isotopic analysis, size exclusion chromatography and Pyrolysis-GC-MS). The analytical range chosen for this study constitutes a powerful tool in the characterisation of DOM in urban water. The inclusion of information from one technique to the next might not only serve as a support to each one, but also as a complement. The DOM fraction from treated effluent and, more generally, DOM from urban water (i. e. receiving treated effluent) display a strong hydrophilic characteristic [i. e. low humic substance (HS) content, low SUVA], along with a high distribution in molecular weights observed by SEC and low average molecular weight. Due to the origin of this DOM, proteinaceous structures constitute the main compounds, as observed by FTIR and Py-GC-MS. Such characteristics (i. e. heterogeneity, low average molecular weight and diverse functional groups, which make up a total of N) could explain that DOM from treated effluent displayed a strong reactive potential metals pollutants as previously demonstrated.
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spelling curtin-20.500.11937-125442017-09-13T14:58:13Z Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures Pernet-Coudrier, B. Varrault, G. Saad, M. Croue, Jean-Philippe Dignac, M. Mouchel, J. Understanding the nature of organic matter is a necessary first step in assessing contaminant bioavailability and allowing water supply managers to optimise the treatment train in the aim of providing safe and inexpensive drinking water. This study provides further insight into the composition, structure and functional groups of dissolved organic matter (DOM) (both hydrophobic and hydrophilic) from urban aquatic systems by means of various analytical techniques (DAX-8/XAD-4 fractionation, elemental analysis, UV and FTIR spectroscopies, 13C and 15N isotopic analysis, size exclusion chromatography and Pyrolysis-GC-MS). The analytical range chosen for this study constitutes a powerful tool in the characterisation of DOM in urban water. The inclusion of information from one technique to the next might not only serve as a support to each one, but also as a complement. The DOM fraction from treated effluent and, more generally, DOM from urban water (i. e. receiving treated effluent) display a strong hydrophilic characteristic [i. e. low humic substance (HS) content, low SUVA], along with a high distribution in molecular weights observed by SEC and low average molecular weight. Due to the origin of this DOM, proteinaceous structures constitute the main compounds, as observed by FTIR and Py-GC-MS. Such characteristics (i. e. heterogeneity, low average molecular weight and diverse functional groups, which make up a total of N) could explain that DOM from treated effluent displayed a strong reactive potential metals pollutants as previously demonstrated. 2011 Journal Article http://hdl.handle.net/20.500.11937/12544 10.1007/s10533-010-9480-z restricted
spellingShingle Pernet-Coudrier, B.
Varrault, G.
Saad, M.
Croue, Jean-Philippe
Dignac, M.
Mouchel, J.
Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures
title Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures
title_full Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures
title_fullStr Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures
title_full_unstemmed Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures
title_short Characterisation of dissolved organic matter in Parisian urban aquatic systems: Predominance of hydrophilic and proteinaceous structures
title_sort characterisation of dissolved organic matter in parisian urban aquatic systems: predominance of hydrophilic and proteinaceous structures
url http://hdl.handle.net/20.500.11937/12544