Synthesis and characterisation of gel-derived mullite precursors from rice husk silica

The sol-gel synthesis and characterization of mullite precursor derived from rice husk silica and aluminum nitrate hydrate [(Al(NO3)3·9H2O] has been investigated. The samples were characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) coupled with Rietveld analys...

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Main Authors: Sembiring, S., Simanjuntak, W., Manurung, P., Asmi, D., Low, It Meng
Format: Journal Article
Published: Elsevier Ltd 2013
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/11809
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author Sembiring, S.
Simanjuntak, W.
Manurung, P.
Asmi, D.
Low, It Meng
author_facet Sembiring, S.
Simanjuntak, W.
Manurung, P.
Asmi, D.
Low, It Meng
author_sort Sembiring, S.
building Curtin Institutional Repository
collection Online Access
description The sol-gel synthesis and characterization of mullite precursor derived from rice husk silica and aluminum nitrate hydrate [(Al(NO3)3·9H2O] has been investigated. The samples were characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) coupled with Rietveld analysis, and scanning electron microscopy (SEM). FTIR results showed the presence of Si-O-Si, Al-O-Al, and Si-O-Al functional groups, which were associated with mullite, corundum, quartz, and cristobalite, as verified by XRD analysis. It is concluded that mullite formation started at 1150 °C, and its abundance increased rapidly with an increase in temperature from 1150 to 1350 °C, resulting in increased phase content from 30.9 to 67.7 wt%. Although mullite was formed at a low temperature, the complete reaction between corundum and silica to form mullite was not achieved. This finding demonstrated that rice husk silica is a potential alternative raw material for the production of mullite ceramic.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T06:56:34Z
publishDate 2013
publisher Elsevier Ltd
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spelling curtin-20.500.11937-118092019-02-19T05:34:46Z Synthesis and characterisation of gel-derived mullite precursors from rice husk silica Sembiring, S. Simanjuntak, W. Manurung, P. Asmi, D. Low, It Meng C.X-rayscattering C.Fouriertransforminfraredspectroscopy(FTIR) C.Electronmicroscopy D.Phasetransitions B. Sol–gel growth The sol-gel synthesis and characterization of mullite precursor derived from rice husk silica and aluminum nitrate hydrate [(Al(NO3)3·9H2O] has been investigated. The samples were characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) coupled with Rietveld analysis, and scanning electron microscopy (SEM). FTIR results showed the presence of Si-O-Si, Al-O-Al, and Si-O-Al functional groups, which were associated with mullite, corundum, quartz, and cristobalite, as verified by XRD analysis. It is concluded that mullite formation started at 1150 °C, and its abundance increased rapidly with an increase in temperature from 1150 to 1350 °C, resulting in increased phase content from 30.9 to 67.7 wt%. Although mullite was formed at a low temperature, the complete reaction between corundum and silica to form mullite was not achieved. This finding demonstrated that rice husk silica is a potential alternative raw material for the production of mullite ceramic. 2013 Journal Article http://hdl.handle.net/20.500.11937/11809 10.1016/j.ceramint.2013.12.038 Elsevier Ltd fulltext
spellingShingle C.X-rayscattering
C.Fouriertransforminfraredspectroscopy(FTIR)
C.Electronmicroscopy
D.Phasetransitions
B. Sol–gel growth
Sembiring, S.
Simanjuntak, W.
Manurung, P.
Asmi, D.
Low, It Meng
Synthesis and characterisation of gel-derived mullite precursors from rice husk silica
title Synthesis and characterisation of gel-derived mullite precursors from rice husk silica
title_full Synthesis and characterisation of gel-derived mullite precursors from rice husk silica
title_fullStr Synthesis and characterisation of gel-derived mullite precursors from rice husk silica
title_full_unstemmed Synthesis and characterisation of gel-derived mullite precursors from rice husk silica
title_short Synthesis and characterisation of gel-derived mullite precursors from rice husk silica
title_sort synthesis and characterisation of gel-derived mullite precursors from rice husk silica
topic C.X-rayscattering
C.Fouriertransforminfraredspectroscopy(FTIR)
C.Electronmicroscopy
D.Phasetransitions
B. Sol–gel growth
url http://hdl.handle.net/20.500.11937/11809