Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction

The solubilization of excess sludge by the solar photo-Fenton reaction has been investigated for the reduction of excess sludge in the activated sludge process. The solubilization kinetics depended on the dosages of the Fenton reagents, Fe and H2O2. Increases of initial Fe and H2O2 concentrations in...

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Main Authors: Tokumura, M., Katoh, H., Katoh, T., Znad, Hussein, Kawase, Y.
Format: Journal Article
Published: Elsevier BV 2009
Online Access:http://hdl.handle.net/20.500.11937/11505
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author Tokumura, M.
Katoh, H.
Katoh, T.
Znad, Hussein
Kawase, Y.
author_facet Tokumura, M.
Katoh, H.
Katoh, T.
Znad, Hussein
Kawase, Y.
author_sort Tokumura, M.
building Curtin Institutional Repository
collection Online Access
description The solubilization of excess sludge by the solar photo-Fenton reaction has been investigated for the reduction of excess sludge in the activated sludge process. The solubilization kinetics depended on the dosages of the Fenton reagents, Fe and H2O2. Increases of initial Fe and H2O2 concentrations in their ranges studied in this work continuously enhanced the sludge solubilization. Cell lysis by the photo-Fenton reaction caused the increase in dissolved chemical oxygen demand (COD) in the first step of sludge solubilization. The further oxidative decomposition of the discharged organic compounds by the photo-Fenton reaction led to the decrease in the dissolved COD as the second step of sludge solubilization. The increase of dissolved COD in the first step of sludge solubilization and the consumption of H2O2 could be described by the pseudo-zero order kinetics based on the accumulated light energy. About 40% reduction of mixed-liquor suspended solids (MLSS) by the solar photo-Fenton reaction was found. It was found that solar light used as a light energy source instead of costly and hazardous artificial UV light was very effective. The dissolved COD for solar photo-Fenton reaction increased faster and by 1.5 times as compared with that by artificial UV light. © 2008 Elsevier B.V. All rights reserved.
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institution Curtin University Malaysia
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publishDate 2009
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spelling curtin-20.500.11937-115052017-09-13T14:55:43Z Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction Tokumura, M. Katoh, H. Katoh, T. Znad, Hussein Kawase, Y. The solubilization of excess sludge by the solar photo-Fenton reaction has been investigated for the reduction of excess sludge in the activated sludge process. The solubilization kinetics depended on the dosages of the Fenton reagents, Fe and H2O2. Increases of initial Fe and H2O2 concentrations in their ranges studied in this work continuously enhanced the sludge solubilization. Cell lysis by the photo-Fenton reaction caused the increase in dissolved chemical oxygen demand (COD) in the first step of sludge solubilization. The further oxidative decomposition of the discharged organic compounds by the photo-Fenton reaction led to the decrease in the dissolved COD as the second step of sludge solubilization. The increase of dissolved COD in the first step of sludge solubilization and the consumption of H2O2 could be described by the pseudo-zero order kinetics based on the accumulated light energy. About 40% reduction of mixed-liquor suspended solids (MLSS) by the solar photo-Fenton reaction was found. It was found that solar light used as a light energy source instead of costly and hazardous artificial UV light was very effective. The dissolved COD for solar photo-Fenton reaction increased faster and by 1.5 times as compared with that by artificial UV light. © 2008 Elsevier B.V. All rights reserved. 2009 Journal Article http://hdl.handle.net/20.500.11937/11505 10.1016/j.jhazmat.2008.06.026 Elsevier BV restricted
spellingShingle Tokumura, M.
Katoh, H.
Katoh, T.
Znad, Hussein
Kawase, Y.
Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction
title Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction
title_full Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction
title_fullStr Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction
title_full_unstemmed Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction
title_short Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction
title_sort solubilization of excess sludge in activated sludge process using the solar photo-fenton reaction
url http://hdl.handle.net/20.500.11937/11505