Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation

In this study, the impact of bromide and iodide on disinfected waters was examined and potential treatment technologies for their removal or mitigation were investigated. Distributed waters from two Western Australian drinking water sources were evaluated in terms of their bromide and iodide concent...

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Main Authors: Gruchlik, Yolanta, Tan, J, Allard, Sebastian, Heitz, Anna, Bowman, M., Halliwell, D., Gunten, U., Criquet, Justine, Joll, Cynthia
Format: Journal Article
Published: Australian Water Association 2014
Online Access:http://digitaledition.awa.asn.au/?iid=107971&startpage=page0000040#folio=40
http://hdl.handle.net/20.500.11937/10764
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author Gruchlik, Yolanta
Tan, J
Allard, Sebastian
Heitz, Anna
Bowman, M.
Halliwell, D.
Gunten, U.
Criquet, Justine
Joll, Cynthia
author_facet Gruchlik, Yolanta
Tan, J
Allard, Sebastian
Heitz, Anna
Bowman, M.
Halliwell, D.
Gunten, U.
Criquet, Justine
Joll, Cynthia
author_sort Gruchlik, Yolanta
building Curtin Institutional Repository
collection Online Access
description In this study, the impact of bromide and iodide on disinfected waters was examined and potential treatment technologies for their removal or mitigation were investigated. Distributed waters from two Western Australian drinking water sources were evaluated in terms of their bromide and iodide concentrations, disinfection by-product (DBP) formation, halogen-specific adsorbable organic halogen (AOX) formation and chlorinous odours after disinfection. In both systems, the brominated DBPs dominated the measured DBPs and, in both cases, the known DSPs accounted for only 30% of total organohalogens. Chloramination with a sufficient free chlorine contact time followed by ammonia addition, rather than preformed monochloramine, may be a viable mitigation strategy for the minimisation of I-OBPs, since exposure to free chlorine should promote the conversion of iodide to iodate, a safe form of iodine. This study has shown that bromide plays an important role in this process, mainly by enhancing the preferred conversion' of iodide to iodate. Ozone pre-treatment selectively oxidised iodide to iodate and minimised the formation of I-OB Ps. Complete conversion of iodide to iodate, while minimising the bromate formation to below the guideline value of 10 µg L-1 was achieved for a wide range of ozone concentrations in raw waters, including raw waters with high bromide concentrations.
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spelling curtin-20.500.11937-107642017-01-30T11:20:53Z Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation Gruchlik, Yolanta Tan, J Allard, Sebastian Heitz, Anna Bowman, M. Halliwell, D. Gunten, U. Criquet, Justine Joll, Cynthia In this study, the impact of bromide and iodide on disinfected waters was examined and potential treatment technologies for their removal or mitigation were investigated. Distributed waters from two Western Australian drinking water sources were evaluated in terms of their bromide and iodide concentrations, disinfection by-product (DBP) formation, halogen-specific adsorbable organic halogen (AOX) formation and chlorinous odours after disinfection. In both systems, the brominated DBPs dominated the measured DBPs and, in both cases, the known DSPs accounted for only 30% of total organohalogens. Chloramination with a sufficient free chlorine contact time followed by ammonia addition, rather than preformed monochloramine, may be a viable mitigation strategy for the minimisation of I-OBPs, since exposure to free chlorine should promote the conversion of iodide to iodate, a safe form of iodine. This study has shown that bromide plays an important role in this process, mainly by enhancing the preferred conversion' of iodide to iodate. Ozone pre-treatment selectively oxidised iodide to iodate and minimised the formation of I-OB Ps. Complete conversion of iodide to iodate, while minimising the bromate formation to below the guideline value of 10 µg L-1 was achieved for a wide range of ozone concentrations in raw waters, including raw waters with high bromide concentrations. 2014 Journal Article http://hdl.handle.net/20.500.11937/10764 http://digitaledition.awa.asn.au/?iid=107971&startpage=page0000040#folio=40 Australian Water Association fulltext
spellingShingle Gruchlik, Yolanta
Tan, J
Allard, Sebastian
Heitz, Anna
Bowman, M.
Halliwell, D.
Gunten, U.
Criquet, Justine
Joll, Cynthia
Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation
title Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation
title_full Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation
title_fullStr Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation
title_full_unstemmed Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation
title_short Impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation
title_sort impact of bromide and iodide during drinking water disinfection and potential treatment processes for their removal or mitigation
url http://digitaledition.awa.asn.au/?iid=107971&startpage=page0000040#folio=40
http://hdl.handle.net/20.500.11937/10764