Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method

TiO2 nanotube was fabricated using anodic oxidation method. The samples were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET). The obtained TiO2 nanotube exhibited increased photoelectrocatalytic (PEC) activities compared to TiO2 film for...

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Main Authors: Wang, N., Li, Xin Yong, Wang, Y., Quan, X., Chen, G.
Format: Journal Article
Published: Elsevier BV 2009
Online Access:http://hdl.handle.net/20.500.11937/10737
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author Wang, N.
Li, Xin Yong
Wang, Y.
Quan, X.
Chen, G.
author_facet Wang, N.
Li, Xin Yong
Wang, Y.
Quan, X.
Chen, G.
author_sort Wang, N.
building Curtin Institutional Repository
collection Online Access
description TiO2 nanotube was fabricated using anodic oxidation method. The samples were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET). The obtained TiO2 nanotube exhibited increased photoelectrocatalytic (PEC) activities compared to TiO2 film for 4-chlorophenol (4-CP) degradation in aqueous solution. Comparing with electrochemical process (EP), direct photolysis (DP) and photocatalytic (PC), a significant PEC synergetic effect was observed. The factors influencing the degradation of 4-CP by the PEC process including bias potential, pH, initial concentration of 4-CP, UV light intensity and electrolyte concentration were examined. The results revealed that the bias potential played an important role in the degradation of 4-CP and the most efficient degradation of 4-CP was achieved in highly acidic and alkaline medium. Initial concentration of 4-CP was also a significant factor affecting the degradation of 4-CP. Moreover, the degradation rate increased with both UV light intensity and electrolyte concentration increasing. © 2008 Elsevier B.V. All rights reserved.
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spelling curtin-20.500.11937-107372017-09-13T14:55:04Z Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method Wang, N. Li, Xin Yong Wang, Y. Quan, X. Chen, G. TiO2 nanotube was fabricated using anodic oxidation method. The samples were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET). The obtained TiO2 nanotube exhibited increased photoelectrocatalytic (PEC) activities compared to TiO2 film for 4-chlorophenol (4-CP) degradation in aqueous solution. Comparing with electrochemical process (EP), direct photolysis (DP) and photocatalytic (PC), a significant PEC synergetic effect was observed. The factors influencing the degradation of 4-CP by the PEC process including bias potential, pH, initial concentration of 4-CP, UV light intensity and electrolyte concentration were examined. The results revealed that the bias potential played an important role in the degradation of 4-CP and the most efficient degradation of 4-CP was achieved in highly acidic and alkaline medium. Initial concentration of 4-CP was also a significant factor affecting the degradation of 4-CP. Moreover, the degradation rate increased with both UV light intensity and electrolyte concentration increasing. © 2008 Elsevier B.V. All rights reserved. 2009 Journal Article http://hdl.handle.net/20.500.11937/10737 10.1016/j.cej.2008.05.025 Elsevier BV restricted
spellingShingle Wang, N.
Li, Xin Yong
Wang, Y.
Quan, X.
Chen, G.
Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method
title Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method
title_full Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method
title_fullStr Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method
title_full_unstemmed Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method
title_short Evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with TiO2 nanotube fabricated by anodic oxidation method
title_sort evaluation of bias potential enhanced photocatalytic degradation of 4-chlorophenol with tio2 nanotube fabricated by anodic oxidation method
url http://hdl.handle.net/20.500.11937/10737