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1860797368937480192
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INTELEK Repository
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Online Access
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https://intelek.unisza.edu.my/intelek/pages/search.php?search=!collection407072
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2015-11-05 09:08:14
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Restricted Document
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12439
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UniSZA
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1. Gerpen., J. V. (2005). Biodiesel Processing and Production. Fuel Processing Technology 86: 1097– 1107. 2. Shawn P. and Conley, B. T. (2006). What is Biodiesel? BioEnergy, ID337. 3. Xiaohu Fan, Burton, R. and Zhou, Y. (2010). Glycerol (Byproduct of Biodiesel Production) as a Source of Fuels and Chemicals-Mini Review. The Open Fuels and Energy Science Journal 3: 17-22. 4. Adhikari, S., Fernando, S. D. and Haryanto, A. (2009). Hydrogen Production from Glycerol: An update. Energy Conversion and Management 50: 2600-2604. 5. Adhikari S, Fernando S, To, F., Bricka R. M, Steele P. H. and Haryanto A. (2008). Conversion of Glycerol to Hydrogen via a Steam Reforming Process over Nickel Catalysts. Energy Fuel 22(2): 1220–1226. 6. Iriondo, A., Barrio, V. L., Cambra, J. F., Arias, P. L., Guemez, M. B., Navarro, R. M., Sanchez-Sanchez, M. C. and Fierro, J. L. G. (2009). Influence of La2O3 Modified Support and Ni and Pt Active Phases on Glycerol Steam Reforming to Produce Hydrogen. Catalysis Communications 10: 1275-1278. 7. Nichele, V., Signoretto, M., Menegazzo, F., Gallo, A., Santo, V. D., Cruciani, G. and Cerrato, G. (2012). Glycerol Steam Reforming for Hydrogen Production: Design of Ni Supported Catalysts. Applied Catalysis B: Environment 111: 225-232. 8. Buhari, J. (2013). Hydrogen Production from Glycerol using Nickel Loaded Zeolite Catalyst. Degree Thesis. Universiti Teknologi Malaysia. 9. Kusworo, T. D., Songip, A. R. and Amin, N. A. S. (2010). Optimization of Partial Oxidation of Methane for Hydrogen Production on NiO-CoO/MgO Catalyst using Design of Experiment. IJET-IJENS. 10(1): 1-8. 10. Jong-San Chang, S.-E. P., Kyu-Wan Lee, and Myoung Jae Choi (1994). Catalytic Reforming of Methane with Carbon Dioxide over Pentasil Zeolite-Supported Nickel Catalyst. Studies in Surface Science and Catalysis, 84: 1587-1594 . 11. Apanee, L. and Kaengsilalai, A. (2008). Activity of Different Zeolite-Supported Ni Catalyst for Methane Reforming with Carbon Dixode. Chemical Engineering Journal 144: 96-102. 12. Na Shi, Q. L., Ting Jiang, T. W., Long, M., Qi Z. and Zhang, X., H. (2012). Hydrodeoxygenation of Vegetable Oils to Liquid Alkane Fuels over Ni/HZSM-5 Catalysts: Methyl Hexadecanoate as the Model Compound. Catalysis Communications 20: 80–84. 13. Nezamzadeh-Ejhieh, A. and Shams-Ghahfarokhi, Z. (2013). Photodegradation of Methyl Green by NickelDimethylglyoxime/ZSM-5 Zeolite as a Heterogeneous Catalyst. Journal of Chemistry: 1-11. 14. Anne, M. G. P., Marcelo, J. B. S., Dulce, M. A. M. and Antonio. S. A. (2006). Cobalt and Nickel Supported on HY Zeolite: Synthesis, Characterization and Catalytic Properties. Materials Research Bulletin 41: 1105–1111. 15. Yun, H. B. A. H. (2013). Hydrogen Production from Glycerol Using Copper and Nickel Loaded Zeolite Based Catalyst. Master Thesis. Universiti Teknologi Malaysia. 16. Williams, C. W. P. T. (2009). Ni/CeO2/ZSM-5 Catalysts for the Production of Hydrogen from the Pyrolysis– Gasification of Polypropylene. International Journal of Hydrogen Energy 15: 6242-6252. 17. Haaland, P. D. (1989). Experimental Design in Biotechnology. New York: Marcel Dekker Inc. 18. Slinn, M., Kendall, K., Mallon, C. and Andrews, J. (2008). Steam Reforming of Biodiesel By-Product to make Renewable Hydrogen. Bioresource Technology 99: 5851-5858.
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6742-01-FH02-ESERI-15-04073.jpg
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norman
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oai_dc
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https://intelek.unisza.edu.my/intelek/pages/view.php?ref=12439
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12439 https://intelek.unisza.edu.my/intelek/pages/view.php?ref=12439 https://intelek.unisza.edu.my/intelek/pages/search.php?search=!collection407072 Restricted Document Article Journal image/jpeg inches 96 96 norman 772 1428 78 78 2015-11-05 09:08:14 1428x772 6742-01-FH02-ESERI-15-04073.jpg UniSZA Private Access Hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst Malaysian Journal of Analytical Sciences Glycerol is the main by-product of biodiesel production that produces from transesterification process. In this research, focused was on hydrogen production via glycerol steam reforming using nickel loaded HZSM-5 catalyst. The catalysts were prepared by using different loading amount of nickel (0.5, 1.0, 5.0, 10.0 and 15 wt %) on HZSM-5 catalyst through the wet impregnation method at temperature 500 ºC and atmospheric pressure. The catalyst was characterized by using XRD, FTIR and SEM. Then, only 15 wt % Ni loading has been chosen based on the parameter which is different range of catalyst weight (0.3-0.5g) at different range of glycerol flow rate (0.2-0.4mL/min) at temperature 600 ºC and atmospheric pressure. The products were analyzed by using gas-chromatography with thermal conductivity detector (GC-TCD) where it is used to identify the yield of hydrogen. The data of the experiment were analyzed by using Response Surface Methodology (RSM) in order to study the relationship of catalyst weight and glycerol flow rate. The results showed that the optimum condition to produce a maximum hydrogen yield with 15wt% Ni/HZSM-5 catalyst was 78.10004% at glycerol flow rate of 0.356484 mL/min and catalyst weight of 0.429267 g. 19 5 Malaysian Society of Analytical Sciences Malaysian Society of Analytical Sciences 1043-1055 1. Gerpen., J. V. (2005). Biodiesel Processing and Production. Fuel Processing Technology 86: 1097– 1107. 2. Shawn P. and Conley, B. T. (2006). What is Biodiesel? BioEnergy, ID337. 3. Xiaohu Fan, Burton, R. and Zhou, Y. (2010). Glycerol (Byproduct of Biodiesel Production) as a Source of Fuels and Chemicals-Mini Review. The Open Fuels and Energy Science Journal 3: 17-22. 4. Adhikari, S., Fernando, S. D. and Haryanto, A. (2009). Hydrogen Production from Glycerol: An update. Energy Conversion and Management 50: 2600-2604. 5. Adhikari S, Fernando S, To, F., Bricka R. M, Steele P. H. and Haryanto A. (2008). Conversion of Glycerol to Hydrogen via a Steam Reforming Process over Nickel Catalysts. Energy Fuel 22(2): 1220–1226. 6. Iriondo, A., Barrio, V. L., Cambra, J. F., Arias, P. L., Guemez, M. B., Navarro, R. M., Sanchez-Sanchez, M. C. and Fierro, J. L. G. (2009). Influence of La2O3 Modified Support and Ni and Pt Active Phases on Glycerol Steam Reforming to Produce Hydrogen. Catalysis Communications 10: 1275-1278. 7. Nichele, V., Signoretto, M., Menegazzo, F., Gallo, A., Santo, V. D., Cruciani, G. and Cerrato, G. (2012). Glycerol Steam Reforming for Hydrogen Production: Design of Ni Supported Catalysts. Applied Catalysis B: Environment 111: 225-232. 8. Buhari, J. (2013). Hydrogen Production from Glycerol using Nickel Loaded Zeolite Catalyst. Degree Thesis. Universiti Teknologi Malaysia. 9. Kusworo, T. D., Songip, A. R. and Amin, N. A. S. (2010). Optimization of Partial Oxidation of Methane for Hydrogen Production on NiO-CoO/MgO Catalyst using Design of Experiment. IJET-IJENS. 10(1): 1-8. 10. Jong-San Chang, S.-E. P., Kyu-Wan Lee, and Myoung Jae Choi (1994). Catalytic Reforming of Methane with Carbon Dioxide over Pentasil Zeolite-Supported Nickel Catalyst. Studies in Surface Science and Catalysis, 84: 1587-1594 . 11. Apanee, L. and Kaengsilalai, A. (2008). Activity of Different Zeolite-Supported Ni Catalyst for Methane Reforming with Carbon Dixode. Chemical Engineering Journal 144: 96-102. 12. Na Shi, Q. L., Ting Jiang, T. W., Long, M., Qi Z. and Zhang, X., H. (2012). Hydrodeoxygenation of Vegetable Oils to Liquid Alkane Fuels over Ni/HZSM-5 Catalysts: Methyl Hexadecanoate as the Model Compound. Catalysis Communications 20: 80–84. 13. Nezamzadeh-Ejhieh, A. and Shams-Ghahfarokhi, Z. (2013). Photodegradation of Methyl Green by NickelDimethylglyoxime/ZSM-5 Zeolite as a Heterogeneous Catalyst. Journal of Chemistry: 1-11. 14. Anne, M. G. P., Marcelo, J. B. S., Dulce, M. A. M. and Antonio. S. A. (2006). Cobalt and Nickel Supported on HY Zeolite: Synthesis, Characterization and Catalytic Properties. Materials Research Bulletin 41: 1105–1111. 15. Yun, H. B. A. H. (2013). Hydrogen Production from Glycerol Using Copper and Nickel Loaded Zeolite Based Catalyst. Master Thesis. Universiti Teknologi Malaysia. 16. Williams, C. W. P. T. (2009). Ni/CeO2/ZSM-5 Catalysts for the Production of Hydrogen from the Pyrolysis– Gasification of Polypropylene. International Journal of Hydrogen Energy 15: 6242-6252. 17. Haaland, P. D. (1989). Experimental Design in Biotechnology. New York: Marcel Dekker Inc. 18. Slinn, M., Kendall, K., Mallon, C. and Andrews, J. (2008). Steam Reforming of Biodiesel By-Product to make Renewable Hydrogen. Bioresource Technology 99: 5851-5858.
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| spellingShingle |
Hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst
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| summary |
Glycerol is the main by-product of biodiesel production that produces from transesterification process. In this research, focused was on hydrogen production via glycerol steam reforming using nickel loaded HZSM-5 catalyst. The catalysts were prepared by using different loading amount of nickel (0.5, 1.0, 5.0, 10.0 and 15 wt %) on HZSM-5 catalyst through the wet impregnation method at temperature 500 ºC and atmospheric pressure. The catalyst was characterized by using XRD, FTIR and SEM. Then, only 15 wt % Ni loading has been chosen based on the parameter which is different range of catalyst weight (0.3-0.5g) at different range of glycerol flow rate (0.2-0.4mL/min) at temperature 600 ºC and atmospheric pressure. The products were analyzed by using gas-chromatography with thermal conductivity detector (GC-TCD) where it is used to identify the yield of hydrogen. The data of the experiment were analyzed by using Response Surface Methodology (RSM) in order to study the relationship of catalyst weight and glycerol flow rate. The results showed that the optimum condition to produce a maximum hydrogen yield with 15wt% Ni/HZSM-5 catalyst was 78.10004% at glycerol flow rate of 0.356484 mL/min and catalyst weight of 0.429267 g.
|
| title |
Hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst
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| title_full |
Hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst
|
| title_fullStr |
Hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst
|
| title_full_unstemmed |
Hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst
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| title_short |
Hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst
|
| title_sort |
hydrogen gas production from glycerol via steam reforming using nickel loaded zeolite catalyst
|